Part A
Part B
| 6. |
(4marks)
where Dl/l arises from change in vacancies
concentration, nv/nsites . Denoting
the latter (temperature dependent) quantity by C(T) , and the volume of
a representative cube of this metal by V, we have
(3marks)
The slope of the plot of lnC(T) vs 1/T gives -Ev/k.
(3marks)
C(T)=C0exp(-Ev/kT)
C(660 )=C(400 )exp[-Ev/(673K*k)]
exp[+Ev/(933K*k)]» 9*10-4
(3marks)
That is, about one in every thousand lattice sites is unoccupied just
below melting occurs. (2marks)
And average distance between two vacancies
lattice constants.
(2marks)
|
| 7. |
 |
Planar density
(1x3marks)
Linear atomic density
(1x3marks)
Thus {110} have the highest planar density,
(2marks)
and <111> the highest linear density.
(2marks)
|
The slip systems are therefore ;
(2+2marks)
and the Burgers vector in a slip has the magnitude
(3marks)
|
| 8. |
(i) Max stress expressed by landing gear
(2marks)
\landing gear will break on first landing!
(1mark)
(ii)
is in between T.S. and F.S. ,
(2marks)
\Gear will fail due to fatgue after repeated
landing;
(1mark)
(iii)
(2marks)
\Gear should never fail.
(1mark)
|
| 9. |
Griffith's crack model is successful in explaining
brittle fracture. (1mark) Microscopic flaws are assumed to have formed
during routine production and handling. (1mark)For the ideal case of elliptical
cracks, the maximum stress at the tip, when a stress s
is applied to the ceramic sample, is
where c is the length of the existing crack, and r
radius of currature at the tip.
(4marks)
Thus, even if the intrinsic strengths under tension and under compression
are comparable, failure occurs at a much reduce tensile stress applied
externally, because it induces a greatly magnified
microscopic tensile stress at the tip, which opens up the crack, to increase
c, resulting in further amplification of sm,
and this process cannot stop until the crack reaches the other end of the
sample.
(4marks)
Unless the propagating fracture hits another ( pre-existing ) microcrack.
Then it may because r suddenly becomes much
larger, and the factor (c/r )1/2
is reduced.
(4marks)
Take c~0.1m (microscopic cracks), and r
~1nm (atomically sharp). Then 2(c/r )1/2
~20 » 10, i.e. tensile and compressive
strength differ by an order of magnitude.
(3marks)
|
| 10. |
(i) Tempering:
(ii) Opacity due to second-phase pores
Multiple scattering at pore-glass interface means transmitted image
becomes diffuse.
(4marks)
Viscosity
(2marks)
Given that
at T=514+273K=787K,
and
at T=696+273K=969K,
and
Then
at T=1204K/931?
(3marks)
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END
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